Wednesday, December 14, 2011

Everything Floats


Today I'm gonna introduce a physical concept that is used a lot in Chemistry. Like some physical properties, this one is hard to explain; I never had a clear concept on college and only understood it correctly in university.


Let’s use this example:

What weights more, a pound of rocks or a pound of feathers?

                                  

Both are the same, a pound is a pound, the difference is that to have a pound of rocks we would only need a few smaller rocks, but to get a pound of feathers we will need a lot of them.

The difference of the volume occupied by these 2 objects is because of the difference of DENSITY between them.

The density of a material is its weight divided by the volume occupied by that mass. The density of liquid water is 1, this means I liter of water weights 1 Kilogram, but the density of ice is 0.9 because 1 liter weights 900 grams. This is the explanation of why the ice floats in your drink.

Hydrostatic principle

If we tie a rock to a string and we immerse it into water we observe that the necessary effort to hold it is less than when it is in the air; it’s like if its weight was decreased. In the same way, if we try to sink a glass pushing its bottom into the water we will notice a big resistance.
These 2 phenomenons obey the same reason: Every liquid exert over the objects immersed in them a force in the contrary direction of the weight, called Push or Bouyancy.

Archimedes discovered that the push experimented by any object immerse in a liquid or a gas is equal to the weight of the fluid being displaced but in opposite direction.

Floating

 
Therefore, on any object immerse in a liquid act 2 forces: its own weight, directed to the center of the Earth (gravity) and the push force of the fluid, directed in the opposite direction. When the weight is bigger than the Push, the object sinks. When the push is equal to the weight, the object remains suspended in equilibrium without movement. And when the push is bigger than the weight, the object goes up to the surface until the weight of the immersed section equals the weight of the displaced fluid.

 Any object can float, as long as it is immersed on a substance more dense than itself, like this bronze object that is floating in Mercury. 



 Source: Ciencia Recreativa (1992) - Planeta Agostini

Sunday, December 11, 2011

Material Safety Data Sheet: OSHA Requirements

The recommended format and the most used is the ANSI MSDS, but the OSHA (Occupational Safety and Health Administration) categories are the minimum and the legally enforceable. Most of MSDS are using the ANSI format but if you find an OSHA MSDS these is what you will find in it.

Let’s use the MSDS of the ACETONE
 
MSDS_OSHA_BANNER


Section I. Manufacturer's Name and Contact Information 

 MSDS_OSHA_Section_1

General Information about the substance such as chemical formula and common names.

Section II. Hazardous Ingredients 

 MSDS_OSHA_Section_2

All the ingredients in the composition of the substance must be listed, especially the carcinogens agents that are required to be listed at levels of 0.1% or greater.

Section III. Physical and Chemical Characteristics

 MSDS_OSHA_Section_3

All the information about boiling and freezing points, volatility and more.

Section IV. Fire and Explosion Hazard Data 

MSDS_OSHA_Section_4

Everything about the potential fire hazard of the chemical, and the conditions under it could ignite or explode. Also like in the ANSI MSDS, some firefighting methods are listed aswell.

Section V. Reactivity Data
 
MSDS_OSHA_Section_5

Other substances that the chemical wont be compatible or could react with, along with some  proper storage conditions.

Section VI. Health Hazards 
 
MSDS_OSHA_Section_6

Everything about the Health hazards of the compound, any symptoms depending on the route of entry on the body.

Section VII. Precautions for Safe Handling and Use / First Aid Procedures 

MSDS_OSHA_Section_7

Section dedicated to ensure the chemical will be stored and handled with the proper procedures and precautions. Be sure to know that this section is very important for insurance companies so you better do everything its said in this part.

In some types of MSDS this section is dedicated to the first aid procedures that must be followed in case of an incident involving a person.

Section VIII. Control Measures
 
MSDS_OSHA_Section_8

Further safety instructions like personal protective equipment.


 
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